Related Questions in Chemistry. It is the simplest keto. Lewis structure is the structure of a molecule in which dots are used to show the electron position around the atoms that make up the molecule. This concept also explains why polar solvents, monomers or polymers inhibit the cata- lyzed polymerization of styrene by clay minerals; these polar compounds are stronger Lewis bases. 22 Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1. 00 PM (GMT). 🤓 Based on our data, we think this question is relevant for Professor Purse's class at SDSU. The Lewis Dot Structure for a common Carbon atom is a C with one dot on all four sides:. Name the functional group present in CH3COCH3. The way CH3COCH3 is written gives the Lewis Structure. Dernière Activité. 91 D: Thermochemistry; Std enthalpy of formation Δ f H o 298 Acetone - Wikipedia, the free encyclopedia QuestionHub. Carbon Dioxide (CO 2) - Carbon dioxide is an example of a compound that contains 2 sets of double bonds. Put two carbons in the center and arrange hydrogena toms on the sides. Acetone, histologic al grade. More information on molar mass and molecular weight. Learn vocabulary, terms, and more with flashcards, games, and other study tools. For each of the molecules these are 3 quastions aboout chem1b (general chemistry) 1. ozone, O3 b. Acetone (chemical formula `CH_3COCH_3` ) exhibits the properties of both the polar as well as nonpolar substances. 5 years ago. thionylchloride, SOCl2 f. NH2CO2H molecule, (skeletal structure H2NCOOH) Help is much appreciated!. Molecule Lewis structure Line-bond structure and Molecular geometry Polar? molecular structure of acetone, CH3COCH3 (more important> less important))\:0::I~. Draw the complete Lewis electron-dot structure for each molecule. com) Carbon color(red)(1) This atom has four atoms directly attached and no lone pairs. c) The hydrogen bonding in ice leads to a very open structure with wasted space in it. The ideal gas law can also be used to determine the densities of gases. Table of Acids with Ka and pKa Values* CLAS Acid HA A-Ka pKa Acid Strength Conjugate Base Strength Hydroiodic HI I-Hydrobromic HBr Br-Perchloric HClO4 ClO4-Hydrochloric HCl Cl-Chloric HClO3 ClO3-Sulfuric (1) H2SO4 HSO4-Nitric HNO3 NO3-Strong acids completely dissociate in aq solution (Ka > 1, pKa < 1). If we have a Lewis structure we're ready to go from 2D to 3D. Use Formal Charge To Choose The Best Lewis Structure For CH3SO2CH3. In addition to what Quora User has written, I will mention some general points about Lewis structures. If you're seeing this message, it means we're having trouble loading external resources on our website. cannot be accurately described by a Lewis structure consistent with the octet rule. 60 x 10^3 mol e. Draw The Lewis Structure For Acetone. First, determine the number of electrons in the outer (valence) shell about the central atom (C, N, Xe, I, etc. Pure acetone is a colourless, somewhat aromatic, flammable, mobile liquid that boils at 56. Everyone has learned that there are three states of matter - solids, liquids, and gases. The molecule C3H6O, also known as Acetone, is Triangular Planar. Pure acetone is a colourless, somewhat aromatic, flammable, mobile liquid that boils at 56. Acetaldehyde is a widespread, naturally occurring, colorless and flammable liquid with a suffocating smell. com - Help with Lewis structure. The structure is not legitimate, because the formal charges are not shown. It would be a CH3-CO-CH3 with all 3 carbons bonding with each other. This is called an intramolecular force. This problem has been solved!. == Answer == 1 bond. It's gonna be a proton donor. Drawing the Lewis Structure for CH 3 CN. When atoms do not share electrons equally, the bond between them is called polar. It is a ketone due to the presence of a carbonyl group in its structure. 1 > 3 > 2 C. Homework Statement Draw the VSEPR structures. RADIATION-INDUCED REDUCTION OF DIVALENT COPPER SALTS IN SOLUTION By Warren H. Concept introduction: The Lewis structures of elements are used to draw the Lewis structures of ionic compounds. Stevens* Crystal Growth & Design 2018,. Be careful! You probably don't. Login to reply the answers Post; David M. Why acetone don't form resonance? resonance forms are individual lewis structure in cases where two or more lewis structure are equally good descriptions of a single molecule. For example: CH3. How much acetone (CH3COCH3) would be needed to obtain 3. According to this model, valence electrons in the Lewis structure form groups, which may consist of a single bond, a double bond, a triple bond, a lone pair of electrons, or even a single unpaired electron, which in the VSEPR model is counted as a lone pair. This means utilizing the ideal gas law. 113) Consider the set of compounds, NH3, HF, and H2O. Intermolecular forces Go with answer (E). now in your problem. ion, draw a reasonable Lewis structure for it. There will be scheduled maintenance work beginning on Wednesday 26th February 2020 from 11:00 AM through to 12. Vollhardt & Schore, pp 169 - 174 Problems 1 , 3 , 4 , 5. Lewis electron dot structure #1 is the major contributor to the hybrid since there are 8 electrons around each atom and there is no charge separation (extra stability). ozone, O3 b. Answer: NH3 < H2O < HF When determining relative acidity. The values in the table below except as noted have been extracted from online and hardbound compilations. Acetic acid, the most important of the carboxylic acids. Draw a correct Lewis structure for acetonitrile, CH3CN. For sale by the Clearinghouse for Federal Scientific and Technical Information Springfield, Virginia 22151 - CFSTI price $3. Be sure to show all atoms, bonds, lone pairs, and formal charges. Draw a lewis structure of H2SO4 and NH4. Molecular polarity depends on both individual bond polarities and molecular geometry, the latter of which we can predict using VSEPR theory. ion, draw a reasonable Lewis structure for it. Each individual structure is called a resonance contributor. 59 (Mean or Weighted MP) VP(mm Hg,25 deg C): 1. Acetic acid, the most important of the carboxylic acids. The molecular formula for acetone is C 3 H 6 O. Download books for free. org are unblocked. That makes the attractions between neighbouring molecules stronger, and so more heat is needed to separate them. Its Lewis Structure is: This atom is an AX3 or a Triangular Planar because there are no unshared pairs on the central atom and the central atom has three other atoms haning off of it. Acetone is a volatile and flammable clear, colorless liquid. Whether you've loved the book or not, if you give your honest and detailed thoughts then people will find new books that are right for them. How much acetone (CH3COCH3) would be needed to obtain 3. Yet the enol form is chemically important in some chemical reactions. Login to reply the answers Post; David M. The AIMPRO method was employed to calculate the structure and vibrational modes of tetrafluoromethane with T d-symmetry. 655 Å and to. Chemistry - A European Journal 1995 , 1 (5) , 294-303. Acetone, GlenDry, a nhydrous. 02/08/2008. So, put the Carbon in the middle and then set the oxygen either side. In an aldehyde, the carbonyl group is bonded to at least one hydrogen atom. Dimethyl Ether is a colorless volatile poisonous liquid compound used as a solvent, fuel, aerosol, propellant and refrigerant. The Lewis structure for CCl4 is a commonly tested Lewis Molecular Dipole Moment Example 2 (CCl4 and CH2Cl2) An example showing how to find whether or not each molecule has an overall molecular dipole moment (i. Thanks for contributing an answer to Chemistry Stack Exchange! Please be sure to answer the question. We have studied the structure and reactivity of the acetone-methanol cluster series {(C3H6O)m(CH3OH)n}H+ as a function of cluster size. 60 x 10^3 mol e. It is the simplest and smallest ketone. 9 °F], and its boiling point is −103. CH3-CH=CH2. Evaluate the Lewis structure below and determine its legitimacy. The reaction of a Lewis acid and a Lewis base produces a coordinate covalent bond. In your example, (i'm going to modify it to CH3COCH3 aka "acetone"), the first carbon is connected to 3 hydrogens and another carbon, the second carbon is bonded to the first and third carbons and 1 oxygen, and the third carbon is bound to the second carbon and 2 hydrogen atoms. Order Molecule BrI5 CF2CF2 ClO3- CH3COCH3 H2CCCH2 # Valence Elect Lewis Structure Order Molecule BrI5 CF2CF2 ClO3- CH3COCH3 H2CCCH2 Number of Valence. One can also use H3N as the molecular formula of Ammonia, and the molecular weight of the component is 17. In addition to what Quora User has written, I will mention some general points about Lewis structures. 02% K) EMSURE® ACS,Reag. Structure #2 is the least plausible contributor because there is charge separation and positive charge on an electronegative atom (O atom) (unstable).  a) hydroxylammonium ion. a triple bond between the nitrogens. Whether you've loved the book or not, if you give your honest and detailed thoughts then people will find new books that are right for them. To enter an electron into a chemical equation use {-} or e ; To enter an ion specify charge after the compound in curly brackets: {+3} or {3+} or {3}. Calculate the molecular weight of a chemical compound. Concept introduction: The Lewis structures of elements are used to draw the Lewis structures of ionic compounds. c) The hydrogen bonding in ice leads to a very open structure with wasted space in it. This chemistry video tutorial explains how to draw lewis structures of molecules and the lewis dot diagram of polyatomic ions. Shared electron cloud closer to O Electronegativity Electronegativity (EN) •Tendency of atom to attract/pull shared/bonding electron to itself •EN value higher – pull/attract electron higher (EN value from 0. The ion has a trigonal pyramidal shape. If the p orbitals were used to form bonds, then all bond angles shoud be 90E or 180E. no because in order to satisfy the octet rule which says the second and the third period elements under the neither electropositive nor electronegative must not become the non-central atom in the compound. 0 pm was calculated, slightly longer (0. Answer: NH3 < H2O < HF When determining relative acidity. Balance the reaction of CH3COCH3 + AlCl3 = CH3COCH2AlCl3 + H using this chemical equation balancer!. Question An automobile gasoline tank holds 43 of gasoline. Alternatively a dot method can be used to draw the lewis structure. Pure acetone is a colourless, somewhat aromatic, flammable, mobile liquid that boils at 56. Vollhardt & Schore, pp 169 - 174 Problems 1 , 3 , 4 , 5. Rank these compounds in order of increasing acidity and discuss your rationale. Lewis structures, also known as Lewis-dot diagrams, show the bonding relationship between atoms of a molecule and the lone pairs of electrons in the molecule. Draw the Lewis structure for nitric acid (the hydrogen atom is attached to one of the oxygen atoms). Consider the molecules CF4 and SF4. An acid is a molecule or ion capable of donating a hydron (proton or hydrogen ion H+), or, alternatively, capable of forming a covalent bond with an electron pair (a Lewis acid). While London dispersion forces are present between ANY two molecules, the induced attractions between polar molecules and nonpolar molecules are called Debye forces. This video discusses if CH3COCH3 is polar or nonpolar. Show the kinds of orbitals that overlap to form each bond. Redraw your structure so that it shows branching. The pKa of acetone is 20. The transformation of a molecular entity A to give a molecular entity A2. Drawing electron dot structures HOW TO: 1. Formula and structure: The acetone chemical formula is CH 3 COCH 3 and its condensed formula is C 3 H 6 O. Each sigma bond counts. The main idea is that in order to form a bond. ICl3 is one of the compounds that don't follow the octet rule, as the iodine at the center of this model accepts 10 electrons. Write two complete, balanced equations for each of the following reactions, one using condensed formulas and one using Lewis structures:. How to draw these lewis structures? I've tried different ways trying to do the skeletal drawing of these molecules. L\EtO c) a) Methane d) b) Ammonia Ammonium Water. Once we know how many valence electrons there are in CH3COOH we can. 68-01-3100 Project No. Which is a better lewis structure, an atom in a compound having a -2 Formal Write the Lewis structure and chemical formula of the compound with a molar. Structure #1 is the most stable resonance Lewis structure since the octet rule is obeyed and the negative formal charge is carried out by N (electronegativity: 3. P black dsp3 90o, 120o. First, as always, count the number of valence electrons in the compound: C has 4, each N has 5, O as 6 and 4 H atoms give. The hydrogens will create bonds with the outside carbons and the oxygen will be double bonded to the center carbon. OBJ: Assess the validity of a Lewis structure. Draw a Lewis dot structure for phosphine, which is sometimes called phosphorus trihydride. This is called an intramolecular force. 822 Å, whereas the distance of H 10 -C 1 changes from 2. The IUPAC name of this element is - Propanone. Table of Acids with Ka and pKa Values* CLAS Acid HA A-Ka pKa Acid Strength Conjugate Base Strength Hydroiodic HI I-Hydrobromic HBr Br-Perchloric HClO4 ClO4-Hydrochloric HCl Cl-Chloric HClO3 ClO3-Sulfuric (1) H2SO4 HSO4-Nitric HNO3 NO3-Strong acids completely dissociate in aq solution (Ka > 1, pKa < 1). This substance can be uses in a number of different ways in a lab, including. The structure is not legitimate, because the formal charges are not shown. For the following molecules, complete the following: draw the best Lewis structure and determine the formal charge of each element in each molecule. Hybridization is defined in terms of sp orbitals. C black sp2 120o. Answer: Molecule sigma bonds pi bonds benzene 12 3 acetone 9 1 acetic acid 7 1 3. ; With CH 3 CN you'll need a triple bond between the Nitrogen (N. Be sure to show all atoms, bonds, lone pairs, and formal charges. 3 (explodes at the slightest touch) Nitrogen atoms usually have three covalent bonds and one lone pair, and iodine atoms usually have one covalent bond and three lone pairs. To enter an electron into a chemical equation use {-} or e ; To enter an ion specify charge after the compound in curly brackets: {+3} or {3+} or {3}. In your example, (i'm going to modify it to CH3COCH3 aka "acetone"), the first carbon is connected to 3 hydrogens and another carbon, the second carbon is bonded to the first and third carbons and 1 oxygen, and the third carbon is bound to the second carbon and 2 hydrogen atoms. Answer to: Select the best Lewis structure for acetone, CH3COCH3. (b) Predict and draw the structure of the conjugate base of acetone and of any other contributing resonance form. Get college assignment help at Smashing Essays Question What is the Lewis Dot Structure of XeCl2? Question Give the intermolecular forces of c2hcl, ni3, and ccl4. See also association. When you are finished drawing your 2D structure, click on the Get Lewis Dot Structure button to see the result. Then determine the polarity for each bond and draw dipole arrows if necessary. improve this answer. Question 4. Be sure to show all atoms, bonds, lone pairs, and formal charges. Hybridization is defined in terms of sp orbitals. Atoms other than C and H must be shown explicitly in a skeletal structure. · Being used as a solvent in organic. bicarbonate anion, HCO3-1 d. Atomic orbitals used in the basis set are close to free‐atom Hartree–Fock solutions. Lewis structures Condensed Formulas Line Drawings Organic Chemistry Organic chemistry is the chemistry of carbon-based compounds. ): Carbon, for example has four valence electrons, nitrogen 5, etc. )That is, each little dot in the diagram represents the absence of an electron from an antibonding orbital. Gilbert Lewis's idea explained the covalent bond and set the foundation for valence bond theory. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1. 59 (Mean or Weighted MP) VP(mm Hg,25 deg C): 1. Similarly, HI > HBr >HCl > HF even though Fluorine is way more electronegative. That makes the attractions between neighbouring molecules stronger, and so more heat is needed to separate them. It is the simplest ketone possible with three carbons in a row. It can be formed by combustion in oxygen poor environments and leads to a number of human deaths each year. diazomethane, H2CNN e. The most stable structures contribute most to the resonance hybrid. Acetic acid, the most important of the carboxylic acids. Resonance structures are two or more. Environmental Protection Agency Washington, B. since acetone is an alkanone (ketone) it has a carbonyl group somewhere in the middle of the carbon chain. 1 (PubChem release 2019. The following is an example of how to draw the "best" Lewis structure for NO 3- (learning by example). For the CH3COOH Lewis structure use the periodic table to find the total number of valence electrons for the CH3COOH molecule. PPSC CHEMISTRY PAST PAPERS MCQS solved BY Malik XUFYAN 1. Another way to think of valence electrons is that they are the outermost electrons in an atom, so they are the most susceptible to participation in chemical. C) The diatomic molecule Cl 2 is an example of a polar molecule. Alternatively a dot method can be used to draw the lewis structure. Steric number = 3. Question: What is the Lewis structure for H3PO4? Lewis Structures: Lewis structures allow us to determine the shape of a molecule. DRAW LEWIS, KEKULE AND SKELETAL STRUCTURE OF: (CH3)2NCH2CH3. 3 Chapter 14: Covalent Bonding: Orbitals Local Electron Model (Valence-Bond Theory) 13 Chapter 14: Covalent Bonding: Orbitals Local Electron Model (Valence-Bond Theory) Assigning Hybridization Step 1: Draw Lewis structure. Why then does a substance change phase from a gas to a liquid or to a solid? Why do the boiling points of the noble gases increase in the order He < Ne < Ar < Kr < Xe? Neon and HF have approximately the same molecular masses. 9 SO3 is a nonpolar molecule because it's electron negativity difference is in between 0 to 0. Third, construct a valid Lewis structure of the molecule in question showing all of the bonds and all of the lone pairs (nonbonded pairs) of electrons. 63 x 10^30 atoms f. Calculate the total valence electrons in the molecule. Additional Problems for practice: 1. In your example, (i'm going to modify it to CH3COCH3 aka "acetone"), the first carbon is connected to 3 hydrogens and another carbon, the second carbon is bonded to the first and third carbons and 1 oxygen, and the third carbon is bound to the second carbon and 2 hydrogen atoms. First, determine the number of electrons in the outer (valence) shell about the central atom (C, N, Xe, I, etc. A molecular formula shows only the kinds and numbers of atoms in a molecule. Each chlorine atom in the molecule provides seven valence electrons, for a total of 21. ; Carbon (C) is the least electronegative atom and goes at the center of the CH 3 CN Lewis structure. resonance forms are individual lewis structure in cases where two or more lewis structure are equally good descriptions of a single molecule. Because the positive and negative charges are attracted to each other, the opposite poles of each molecule form bonds. See the Big List of Lewis Structures. Use your 2D structure (and resonance structures) to generate the 3D sigma skeleton. Atomic orbitals used in the basis set are close to free‐atom Hartree–Fock solutions. 14 Note: All types of bonds (single, double, and triple) between two atoms count as 1 bond. This colorless liquid ketone has a sharp, sweet odor reminiscent of butterscotch and acetone. The AIMPRO method was employed to calculate the structure and vibrational modes of tetrafluoromethane with T d-symmetry. Industrially, it is used in the preparation of metal acetates, used in printing processes; vinyl acetate, used in the production of plastics; cellulose acetate, used in making photographic films and textiles; and volatile organic esters, used as solvents. SO2 is a polar molecule because it's electron negativity difference is in between 0. Asked in Health , Chemistry. (A) CH3CHO (C) CH3CONHCH3 4) Which is the strongest acid? (A) NH4 (B) HC=CH 5) Which is the strongest base? (B) CH3CH2CH2CH2 (C) NH2. CH3COCH3 acetone 3d molecule isolated on white. CH3COCH3, acetone Draw a Lewis Dot structure of: CH3CO2( 1) CH3NH3(+1 What is the Lewis dot structure for CH3COCH3 - The Q&A wiki lewis structure for ch3coch3 Ch3coch3 structure - Test Page for the SSL/TLS-aware Apache. Acetaldehyde is found in various plants, ripe fruits, vegetables, cigarette smoke, gasoline and diesel exhaust. 6 is integrated into the above Learning Objective for organic chemistry in sections 1. 56 dm3 (c) The sphere weighs 1950 kg; the thief is unlikely to be able to carry it. Ethers can be obtained from alcohols by the elimination of a molecule of water from two molecules of the alcohol. 1 (PubChem release 2019. Ethylene is an important industrial organic chemical. You can find the hybridization of acetone by individually finding the hybridization of carbon atoms The first and the third carbon atoms are similar and they have the same hybridization state as they are fully saturated with three hydrogen atoms a. You may have realized that the double bond between oxygen and nitrogen could just as well have been drawn from the top oxygen. Question: What is the Lewis structure for H3PO4? Lewis Structures: Lewis structures allow us to determine the shape of a molecule. D Latham b J. Be careful! You probably don't. 72 (Adapted Stein & Brown method) Melting Pt (deg C): -24.  Acetone is a very useful molecule, which is relatively inexpensive and has many different uses. Q: Cis-4-Bromocyclohexanol racemic C6H10O (compound C) Compound C has infrared absorption in the 1620-1680-cm-1 and in the 3590-3650-cm-1. By writing the electron configuration, we know that the number of electrons in its outermost shell (2s 2p) is 5. 00 (Mean or Weighted MP) VP(mm Hg,25 deg C): 116 (Mean VP of Antoine & Grain. 4 Acetone,,,well CH3COCH3,,it has a hydrogen bond coz hydrogen is combined with oxygen,,,its stated in my book,,you can also know if it has H-bond if it combines. An updated version of their list is given in Table 3. NH3 stands for the Ammonia or also known as Nitrogen Trihydride. Question An automobile gasoline tank holds 43 of. Its chemical formula is (CH3)2O and consists of three carbon. 9 °F], and its boiling point is −103. Intermolecular Forces Dipole-Dipole interaction (e. So when you see that "-one", we're talking about a ketone. When you have finished drawing your Lewis structures draw a single three. first carbon has all single bonds. This pair of molecules are _____. NH3 stands for the Ammonia or also known as Nitrogen Trihydride. First, determine the number of electrons in the outer (valence) shell about the central atom (C, N, Xe, I, etc. An electron pair from the Bronsted-Lowry base is shared with the proton to make a new bond. Yet the enol form is chemically important in some chemical reactions. So, that is what I did. (b) Draw the Lewis structure for the cyanide ion (CN –). SO2 is a polar molecule because it's electron negativity difference is in between 0. The structure is not legitimate, because the middle carbon lacks an octet. Below is a listing of the 20 amino acids grouped by their "R" group properties. Question: Draw the structure of the conjugate acid of acetone (CH_3 COCH_3). You may have realized that the double bond between oxygen and nitrogen could just as well have been drawn from the top oxygen. Lewis structure: The properly way to determine the Lewis structure, based on this example, is: Total valence electrons: $4 + 6\cdot2 + 1\cdot2 = 18$ Total electrons needed for octets/doublets: $8\cdot3+2\cdot2 = 28$ Total shared/bonding electrons: $28-18 = 10$ (In other words, there are only five bonds. Provide the structural formula for acetone. 00794*3 + 12. ) Given the Lewis structure or enough information to produce it, draw the geometric sketch of a molecule, including bond angles. For 2-propanone, you can neglect "2", because that is the only position to have the carbonyl group in propanone. Log Octanol-Water Partition Coef (SRC): Log Kow (KOWWIN v1. To change the symbol of an atom, double-click on the atom and enter the letter of the new atom. Acetone CH3COCH3 3 C + O + 6H first draw all theatoms where you think O they might go H H C H C C H H H Pg 44 Published in: Education. 9 °F], and its boiling point is −103. asked by danielle on February 1, 2010; chemistry. (H+) + (OH-) = H2O + 13. This concept also explains why polar solvents, monomers or polymers inhibit the cata- lyzed polymerization of styrene by clay minerals; these polar compounds are stronger Lewis bases. 68 x 10^4 atoms g. The hydrogens will create bonds with the outside carbons and the oxygen will be double bonded to the center carbon. The smaller the value of a, the more sensitive is the Lewis acid to change in the structure of the base relative to the change for the proton. Ch3s(o)ch3 lewis structure - Course Hero | Study Guides, Lecture. Get college assignment help at Smashing Essays Question What is the Lewis Dot Structure of XeCl2? Question Give the intermolecular forces of c2hcl, ni3, and ccl4. The number of moles can be calculated using the following formula: n = PV/RT. Ammonia gas is known as Azane. Its chemical formula is (CH3)2O and consists of three carbon. Location: Appendix H: Ionization Constants Of Weak Acids. Show the kinds of orbitals that overlap to form each bond. Given that the chemical is naturally present in many organisms, there is little risk of toxicity. Need to convert the following compounds into line-angle formulas. To enter an electron into a chemical equation use {-} or e ; To enter an ion specify charge after the compound in curly brackets: {+3} or {3+} or {3}. In this chapter, interactions of CO2 with a number of organic compounds at molecular level are discussed in detail. 5 °C or 134 °F and readily vaporizes and has a distinctive odor. CH3COCH3 acetone) Hydrogen bonding (e. nitromethane, CH3NO2 c. Conjugate Acid: The term conjugate acid suits for the substance that is formed from a base upon the addition of a. a d b y D a t a C a m p. Acetone, histologic al grade. You'll want to calculate the formal charges on each atom to make sure you have the best Lewis structure for XeO 3. Its lewis structure is. structure, and the best arrangement of the 3 bonding electron pairs around the boron atom is a trigonal planar structure. Which element is most likely to form three covalent bonds? C, Si, S, Se. Balanced Chemical Equation. It can be formed by combustion in oxygen poor environments and leads to a number of human deaths each year. Expert Answer 86% (14 ratings) Previous question Next question. ch 13 practice mc problems which of the following statements is incorrect? ionic bonding results from the transfer of electrons from one atom to another. Show How These Two Molecules Position Themselves When Next To Each Other And Show The Attraction Using A Dotted Line. The Lewis Structure, or Lewis Dot Diagram, shows the bonding between atoms of a molecule and any electrons that may exist. The valence orbitals of the nonmetals are the s and p orbitals. Draw the Lewis structure for nitric acid (the hydrogen atom is attached to one of the oxygen atoms). Get Answer. Atomic structure and atomic spectra Molecular structure Molecular symmetry Spectroscopy 1: rotational and vibrational spectra Spectroscopy 2: electronic transitions Spectroscopy 3: magnetic resonance Statistical thermodynamics: the concepts Statistical thermodynamics: the machinery Data section Answers to exercises Answers to problems Index. Problem: As noted in Table 3. Molecular formula: C 5 H 12 Structural formula: CH 3 CH 2 CH 2 CH 2 CH 3 Condensed structural formula: CH 3 (CH 2) 3 CH 3 Abbreviated planar formula: 2. 3 > 1 > 2 27. Below is a listing of the 20 amino acids grouped by their "R" group properties. 4ml 2M HCI and 1ml water to cuvette • Pipette 0. Find the molecular formula of diazomethane, draw its Lewis structure, and assign formal charges to each atom. Howard Jitendra Saxena May 1976 Final Report Contract No. The melting point of ethylene is −169. What is the Lewis dot structure, shape, and polarity of xenon difluoride, iodine trichloride, and nitrogen trichloride?. I hope this sends you in the right direction. 00794*2 + 15. H white sp. In order of importance, a major. The mechanism for imine formation proceeds through the following steps: 1. A major resonance contributor is one that has the lowest energy. 57 (Adapted Stein & Brown method) Melting Pt (deg C): 118. SO2 is a polar molecule because it's electron negativity difference is in between 0. Synthesis, Structure, and Reactivity of Chiral RheniumN-Pyrrolyl Complexes Regiochemistry of Electrophilic Addition and Unprecedented Rearrangements to Carbon-Ligated Species. Each individual structure is called a resonance contributor. Four methods for drawing structures are shown in Fig. In reaction pathway of INT3→TS5→P2, the distance of C 4 –H 10 changes from 1. The Lewis structure for XeO 3 requires you to place more than 8 valence electrons on Xe. CH3COCH3 + Br2 CH3COCH2Br + H+ + Br - The rate of disappearance of bromine was measured for several different concentrations of acetone, bromine, and H+ ions at a certain temperature. Draw the Lewis dot structures for each of the following molecules: a. Diazomethane is a highly poisonous, explosive compound because it readily evolves N2. The 3D shape of a molecule has a lot to do with how the molecule behaves. Determining the hybridization of Carbon atoms is very easy, First of all you have to count the number of single, double and triple bonds around the carbon. asked by Sue on June 2, 2010; CHEMISTRY. Use structural formulas for the organic compounds. diazomethane, H2CNN e. Question Give the intermolecular forces of c2hcl, ni3, and ccl4. Explain in detail the role of: (1)cryolite in the electrolytic reduction of alumina. ) • Amines are organic derivatives of ammonia, NH 3, in. The melting point of ethylene is −169. The Lewis structure of ICl3 is a drawing or model chemists use to predict the geometry of the molecule. There are 2 oxygen atoms bonded to carbon, with no lone pairs, so the steric number is 2. We can often write more than one Lewis structure for a molecule, differing only in the positions of the electrons. Question 4. Evaluate the Lewis structure below and determine its legitimacy. Recall that density is defined as the mass of a substance divided by its volume: Assume that you have exactly 1 mol of a gas. 04) the most electronegative atom compared to S (electronegativity: 2. It would be a CH3-CO-CH3 with all 3 carbons bonding with each other. Add them together. three unpaired electrons. For the Lewis structure for Acetone, calculate the total number of valence electrons for the Acetone molecule. Aldehydes and Ketones. - [Voiceover] Drawing acid-base reactions is really an important skill when you're doing organic chemistry mechanisms. Separate the molecule to show two identical free. Polar molecules must contain polar bonds due to a difference in electronegativity between the bonded atoms. Lewis structure: The properly way to determine the Lewis structure, based on this example, is: Total valence electrons: $4 + 6\cdot2 + 1\cdot2 = 18$ Total electrons needed for octets/doublets: $8\cdot3+2\cdot2 = 28$ Total shared/bonding electrons: $28-18 = 10$ (In other words, there are only five bonds. Draw the Lewis dot structure for each of the following polyatomic ions: a. bonded to two carbon atoms (Section 1. Step by step tutorial for drawing the lewis structure for acetone. Conjugate Acid: The term conjugate acid suits for the substance that is formed from a base upon the addition of a. doc Drawing 2D, 3D and Resonance Structures from condensed line formulas. CH3COCH3(Acetone) 9 sigma bonds: 6 1s-sp3(between H-C), 3 sp3-sp2(between C-C and C-O) 1 pi bond: 2p-2p (between C-O) 14. Fe3+ CO32- NH4+ So42- ionic compounds formed from the ions Number of water molecules contained in 0. Each individual structure is called a resonance contributor. 6 is integrated into the above Learning Objective for organic chemistry in sections 1. CH 3 OCH 3 is a type of organic compound called an Ether. Why then does a substance change phase from a gas to a liquid or to a solid? Why do the boiling points of the noble gases increase in the order He < Ne < Ar < Kr < Xe? Neon and HF have approximately the same molecular masses. In the Lewis structure for elemental nitrogen there is (are): A. Draw the Lewis structure for nitric acid (the hydrogen atom is attached to one of the oxygen atoms). Write the Lewis structure and chemical formula of the compound with a molar The identity of a molecule or polyatomic ion is uniquely specified by the c hello! I am currently in my 3rd week of university and I've just done a Che Show how the starting material can be converted to the product through any. There are 9 sigma bonds and 2 pi bonds. Draw a lewis structure of H2SO4 and NH4. CH3COCH3, acetone Draw a Lewis Dot structure of: CH3CO2( 1) CH3NH3(+1 What is the Lewis dot structure for CH3COCH3 - The Q&A wiki lewis structure for ch3coch3 Ch3coch3 structure - Test Page for the SSL/TLS-aware Apache. Three-dimensional structure: (b) Geometry of CH3OCH3 predicted using VSEPR theory: Draw the simplified Lewis structure. Asked in Chemistry , Elements and Compounds , Atoms and Atomic Structure. Write equations for the reactions of acetaldehyde, acetone, ethanol, and acetic acid with Fehling's Solution. the orbitals of oxygen and the hydrogens do not undergo hybridization. Atomic orbitals used in the basis set are close to free‐atom Hartree–Fock solutions. It would be a CH3-CO-CH3 with all 3 carbons bonding with each other. Sp3 hybridization explains the tetrahedral structure of molecules with bond angles of 109. CH3OCH3 is a member of the Ether family of organic compounds. For instance equation C6H5C2H5 + O2 = C6H5OH + CO2 + H2O will not be balanced,. Draw Lewis structures for NCl3 and a hypothetical NCl5, and explain why NCl5 is an unlikely structure. LOGIN JOIN. For each of the molecules these are 3 quastions aboout chem1b (general chemistry) 1. The Lewis Dot Structure for a common Carbon atom is a C with one dot on all four sides:. The lower the pKa of an acid, the stronger the acid. Drawing line-angle formulas for compounds. Dimethylformaldehyde. CH3COCH2CHCHCOOH Don't know how to handle these when. 822 Å, whereas the distance of H 10 -C 1 changes from 2. Ethers are similar in structure to alcohols, and both ethers and alcohols are similar in structure to water. This means utilizing the ideal gas law. Here, atoms within a molecule are attracted to one another by the sharing of electrons. asked by danielle on February 1, 2010; chemistry. structure, and the best arrangement of the 3 bonding electron pairs around the boron atom is a trigonal planar structure. Step 3 & 4: The Lewis structure of CH 3 COOCH 3 is as follows: Fig. Howard Jitendra Saxena May 1976 Final Report Contract No. Structure, spectral properties and interconversions of bis-niobocenes and their dianions. E) none of these Use the following to answer question 5: Consider the following molecules. Less dense than water. Dipole-dipole attraction occurs because ethanol is a polar molecule with both one positively charged and one negatively charged end. (iii) Predict the approximate carbon to carbon to carbon bond angle in propanone. A) I B) II C) III D) IV 47. 10)Rank the following in order of decreasing importance as a contributing resonance structure to the molecular structure of acetone, CH3COCH3 (more important> less important))\:0::I~ +~~ ~~~w:1:;c""r1q, ~a~ /C", CH H3C CH3 Ctt ~H3C CH3 H~ 3 3 1 2 a) 1> 2 > 3 @ 1> 3> 2 c) 2 > 1> 3 d) 3 > 1> 2. NH2CO2H molecule, (skeletal structure H2NCOOH) Help is much appreciated!. com - Help with Lewis structure. c) The given structure is as follows: Ch. 91 D: Thermochemistry; Std enthalpy of formation Δ f H o 298 Acetone - Wikipedia, the free encyclopedia QuestionHub. Its vapors are heavier than air. oxygen satisfies the octet rule as the most electronegative and carbon the least electronegative between the two and hence we see the. Use formal charge to choose the best Lewis structure for CH3SO2CH3. Draw The Lewis Structure For Acetone. Its Lewis Structure is: This atom is an AX3 or a Triangular Planar because there are no unshared pairs on the central atom and the central atom has three other atoms haning off of it. The correct option among all the options that are given in the question is the fifth option or the last option or option "E". Draw the Lewis dot structures for each of the following molecules: a. It is shipped as a liquefied gas under its vapor pressure. Question: Draw The Lewis Structure Of Acetone, CH3COCH3 And Chloroform, CHCl3 Using Correct Bond Angle Relationships; Include Partial Charges On Each Atom (if Any). CH3COCH3 is also known as acetone. Here is the diagram… The CH3- Lewis structure has a total of 8 valence electrons. Moreover, there is 2 Oxygen. Its lewis structure is. The structure is not legitimate, because the formal charges are not shown. 67 estimate) = 0. How many moles of Ca are in 8-1 g Ca a. Structures #bb "B"# and #bb "C"# are higher in energy and are minor contributors. For the CH3COOH Lewis structure use the periodic table to find the total number of valence electrons for the CH3COOH molecule. The ideal gas law can also be used to determine the densities of gases. (Adapted from [email protected] Question An automobile gasoline tank holds 43 of gasoline. JIAS ACADEMY 2017 PPSC Past Papers CHEMISTRY MCQS Malik Xufyan www. * * * * * * * Big Idea in Organic Chemistry Structure controls Function Each functional group has predictable reactivity Drawing Organic Structures Butane: C4H10 CH3CH2CH2CH3 CH3(CH2)2CH3 Shortcuts make structures easier & faster to draw Line Structure Only shows bonds C atoms assumed at each end and intersection of bonds H atoms not shown. The first molecule consists of five black balls, which form a cyclical structure. Acetone is typically derived from acetoacetate through the action of microbial acetoacetate decarboxylases found in gut microflora. CH3COCH3 acetone) Hydrogen bonding (e. 91 D: Thermochemistry; Std enthalpy of formation Δ f H o 298 Acetone - Wikipedia, the free encyclopedia QuestionHub. Answer Save. 1 > 2 > 3 B. Question : 30P - (a) Both PCl3 and PCl5 are stable compounds. 48)Give the structure of the alkene which would yield the following products upon ozonolysis-reduction. The way CH3COCH3 is written gives the Lewis Structure. So, you have a total 24 electrons to deal with. Contact with the liquid can cause frostbite. Draw the complete Lewis electron-dot structure for each molecule. In chemistry, the formula weight is a quantity computed by multiplying the atomic weight (in atomic mass units) of each element in a chemical. First, as always, count the number of valence electrons in the compound: C has 4, each N has 5, O as 6 and 4 H atoms give 4 more. In this formula, n is the number of moles, P is the pressure, V is the. Include all valence electrons in your structure. Download a Free Preview or High Quality Adobe Illustrator Ai, EPS, PDF and High Resolution JPEG versions. Given that the chemical is naturally present in many organisms, there is little risk of toxicity. A few things to note: You need to have the correct Lewis structure first. Can anyone give me the lewis structure for NH2CONH2 - Chemistry - Chemical Bonding and Molecular Structure. Drawing the lewis structure for acetone c 3 h 6 o viewing notes. Structure #2 is the least plausible contributor because there is charge separation and positive charge on an electronegative atom (O atom) (unstable). There are 2 oxygen atoms bonded to carbon, with no lone pairs, so the steric number is 2. A step-by-step explanation of how to draw the CH3OCH3 Lewis Structure. Once we know how many valence electrons there are in CH3COOH we can. Determining oxidation numbers from the Lewis structure (Figure 1a) is even easier than deducing it from the molecular formula. 6+4 (7) 3-ée i. In the formation of CO2, there are two particles; Carbon, and Oxygen. In acetone vapor at ambient temperature, only 0. Expert Answer 86% (14 ratings) Previous question Next question. Whether you've loved the book or not, if you give your honest and detailed thoughts then people will find new books that are right for them. Lewis Structures Resonance Structures Formal Charge and Oxidation Numbers Octet Exceptions Coordinate Covalent Bonds Polarisability of Anions, The Polarizing Power of Cations Electronegativity Dipole Moments Bond Lengths & Energies Forces and Liquid Structure. For each of the molecules these are 3 quastions aboout chem1b (general chemistry) 1. That said, there are some areas in which one is. The Lewis structure of ICl3 is a drawing or model chemists use to predict the geometry of the molecule. Give the molecular formula, the structural formula, the condensed structural formula, and the abbreviated planar formula (line structure) for pentane. Identify the type of hybridization exhibited by sulfur in the SF3+ cation. Everyone has learned that there are three states of matter - solids, liquids, and gases. Acetone (chemical formula `CH_3COCH_3` ) exhibits the properties of both the polar as well as nonpolar substances. Two ways of drawing the Lewis structure for H3O+ are shown below. Calculate the total valence electrons in the molecule. That makes the attractions between neighbouring molecules stronger, and so more heat is needed to separate them. 4ml 2M HCI and 1ml water to cuvette • Pipette 0. For questions 13 through 15: Draw the Lewis dot structure for the given compound. 92 Comments 27 Likes Statistics Notes Full Name. Asked in Health , Chemistry. I was wondering why the compound SO4^2- has three Lewis structures whereas PO4^3- has only two. Unlike a Lewis dot diagram, this figure does not portray electrons, but rather holes. Hence, the Lewis structure of NH 3 is: There are three bond pairs and one lone pair. In order to produce the Lewis structure of a molecule, there are certain steps one needs to follow (they are five (5) in number). This video discusses if CH3COCH3 is polar or nonpolar. Its chemical formula is (CH3)2O and consists of three carbon. Use formal charge to determine which of the resonance structures is most important to the structure of nitric acid. Question: Use Formal Charge To Choose The Best Lewis Structure For CH3SO2CH3. A carboxylic acid is an organic compound that contains a carboxyl group (C(=O)OH). 7 – 4) Electronegativity •EN increase up a Group •EN increase across a Period H 2. 08 g mol -1. Structure Simplification and Synthon Interchangeability in Some Organic Journal of the American Chemical Society 1996, and Benjamin P. I'll tell you the Acid or Base list below. a) Add together the number of valence electrons for all the atoms (If it is an ion, you must add or subtract electrons accordingly). Once we know how many valence electrons there are in PCl5 we can distribute them around the central atom and attempt to fill the outer shells of each atom. Here, atoms within a molecule are attracted to one another by the sharing of electrons. 56 dm3 (c) The sphere weighs 1950 kg; the thief is unlikely to be able to carry it. Contact with the liquid can cause frostbite. Use formal charge to determine which of the resonance structures is most important to the structure of nitric acid. 83%) than the gas-phase experimental value of 131. The reaction of a Lewis acid and a Lewis base produces a coordinate covalent bond. asked by danielle on February 1, 2010; chemistry. DRAW LEWIS, KEKULE AND SKELETAL STRUCTURE OF: (CH3)2NCH2CH3. Wamser Chapter 5 Homework Answers - Stereoisomers. As was the case for gaseous substances, the kinetic molecular theory may be used to explain the behavior of solids and liquids. This is an exception since the least electronegative atom is Carbon (remember Hydrogen atoms always go on the outside). Acetone is a volatile and flammable clear, colorless liquid. Draw the Lewis structure for each of the compounds. SF4 4 sigma bonds formed by sp3from fluorine and dsp3from sulfur. How does the equation with acidified dichromate solution and with isopropyl alcohol (CH3CHOHCH3) differ from the oxidation of ethyl alcohol which is a primary alcohol, containing a –CH2OH group?. Write equations for the reactions of acetaldehyde, acetone, ethanol, and acetic acid with Fehling's Solution. This attraction is stronger than London dispersion but weaker than the third type of. An acid is a molecule or ion capable of donating a hydron (proton or hydrogen ion H+), or, alternatively, capable of forming a covalent bond with an electron pair (a Lewis acid). (b) Predict and draw the structure of the conjugate base of acetone and of any other contributing resonance form. ): Carbon, for example has four valence electrons, nitrogen 5, etc. So when you see that "-one", we're talking about a ketone. For instance equation C6H5C2H5 + O2 = C6H5OH + CO2 + H2O will not be balanced,. Balance the reaction of CH3COCH3 + O2 = CO2 + H2O using this chemical equation balancer!. 00000024% of the molecules are in the enol form. A description, explanation, shapes and bond angles of a variety of organic molecules are described with dot and cross and '3D' shape diagrams to represent e. Viewing Notes: In the CH 3 OCH 3 Lewis structure, the oxygen atom goes in the center. Less dense than water. 2 x 10^23 x 10 = 1. Question An automobile gasoline tank holds 43 of gasoline. Draw a Lewis structure. Whether you've loved the book or not, if you give your honest and detailed thoughts then people will find new books that are right for them. An electron pair from the Bronsted-Lowry base is shared with the proton to make a new bond. (c) Why may both ammonia and the cyanide ion serve as a Lewis base? 17. You can get assistance with the Lewis dot structures from your textbook if necessary. For example, it mixes in both water (`H_2O` ) and carbon tetrachloride (`C Cl_4` ). Share with your friends. (A) aldehyde (B) ester (C) ketone (B) CH3COOCH2CH3 (D) CH3NH2 (C) NH3 (D) ether (D) (D) CH30 (D) 3) Select the molecule that is an amide. The structure is not legitimate, because the oxygen does not have an octet. It is a ketone due to the presence of a carbonyl group in its structure. We use several kinds of formulas to describe organic compounds. Answer to: Select the best Lewis structure for acetone, CH3COCH3. For each of the molecules these are 3 quastions aboout chem1b (general chemistry) 1. CH3COCH3, acetone. Dimethyl ether is a colorless gas with a faint ethereal odor. The names for aldehyde and ketone compounds are derived using similar nomenclature rules as for alkanes and alcohols, and include the class-identifying suffixes -al and -one, respectively:. When you have finished drawing your Lewis structures draw a single three. The molecule C3H6O, also known as Acetone, is Triangular Planar. On the right we have sodium hydroxide. CH 3 OCH 3 is a type of organic compound called an Ether. Other readers will always be interested in your opinion of the books you've read. There are three central atoms, 2 carbon atoms and 1 oxygen atom. During this time, you may not be able to log into ChemSpider. Yes, sometimes the order in which they are written often corresponds to how the atoms are connected. Draw the Lewis dot structure of acetone. Its vapors are heavier than air. 13 ; View Full Answer CH3-CO-CH3. I was given 13 chemicals and have to draw the Lewis dot structure, there 3-D structures, Shape, Hybridization, bond angles, Polarity, and there Intermolecular forces. Recently Asked Questions 1. ; The CH 3 CN chemical formula gives you a strong hint that CH3 will be attached to the central atom. More information on molar mass and molecular weight. A molecule has a resonance structure. We can often write more than one Lewis structure for a molecule, differing only in the positions of the electrons. For example, when ethanol is treated with a limited amount of sulfuric acid and heated to 140 °C, diethyl ether and water are formed: In the general formula for ethers, R— O —R, the hydrocarbon groups (R) may be the same or. Drawing the lewis structure for acetone c 3 h 6 o viewing notes. 2 CH3COCH3 (CH3)2C(OH)CH2COCH3. PPSC CHEMISTRY PAST PAPERS MCQS solved BY Malik XUFYAN 1. It is produced by heating either natural gas, especially its ethane and propane components, or petroleum to 800-900 °C (1,470-1,650 °F), giving a mixture of gases from which the ethylene is separated. It is a colorless, volatile, flammable liquid with a characteristic odor. 9 SO3 is a nonpolar molecule because it's electron negativity difference is in between 0 to 0. com The Lewis structure of CH3OCH3 is dimethyl ether, the simplest ether in existence. ): Carbon, for example has four valence electrons, nitrogen 5, etc. 2 C=C bond. (H+) + (OH-) = H2O + 13. Draw a lewis structure of H2SO4 and NH4. Need help finishing my lab I am having a hard time completing my lab. 5 - CH3COCH3 (acetone) is a common laboratory solvent Additional Science Textbook Solutions. b) What did you have to do with one of the terminal ends in order to create the branching requested for your polymer? 6. Draw The Lewis Structure For Acetone. 82 x 10^29 atoms b. Ethylene is an important industrial organic chemical. If you're behind a web filter, please make sure that the domains *. Lewis electron dot structure #1 is the major contributor to the hybrid since there are 8 electrons around each atom and there is no charge separation (extra stability). ) • Amines are organic derivatives of ammonia, NH 3, in. Login to reply the answers Post; David M. NH3 stands for the Ammonia or also known as Nitrogen Trihydride. Select the best Lewis structure for acetone, CH3COCH3. Christopher Philip H. 3 Chapter 14: Covalent Bonding: Orbitals Local Electron Model (Valence-Bond Theory) 13 Chapter 14: Covalent Bonding: Orbitals Local Electron Model (Valence-Bond Theory) Assigning Hybridization Step 1: Draw Lewis structure. 49 (a) Draw the Lewis structure for ammonia (NH3). Rank these compounds in order of increasing acidity and discuss your rationale. For each of the molecules these are 3 quastions aboout chem1b (general chemistry) 1. Percent composition by element. That makes the attractions between neighbouring molecules stronger, and so more heat is needed to separate them. The Lewis Dot Structure for a common Carbon atom is a C with one dot on all four sides:. The Lewis structure of ICl3 is a drawing or model chemists use to predict the geometry of the molecule. I think you are meaning 'CH3-' by 'CH3'. Fundamentals of Organic Chemistry - Study Guide and Solutions Manual - Wiley | Solomons T. The Lewis structure for XeO 3 requires you to place more than 8 valence electrons on Xe. 2 > 1 > 3 D. nitromethane, CH3NO2 c. (The notion of holes has been part of physics since 1930, as discussed in section 10. Propionaldehyde appears as a clear colorless liquid with an overpowering fruity-like odor. Lewis structures Condensed Formulas Line Drawings Organic Chemistry Organic chemistry is the chemistry of carbon-based compounds. thionylchloride, SOCl2 f. a carbonyl group is an oxygen double-bonded to a carbon. The molecular formula for acetone is C 3 H 6 O. A step-by-step explanation of how to draw the Acetone Lewis Structure. For the rest of the semester we will be discussing small molecules that are held together by covalent bonds, or ionic bonds. Structure E is an ester. Find more Chemistry widgets in Wolfram|Alpha. The number of moles can be calculated using the following formula: n = PV/RT. Each atom in the bond has a full valence shell, with nitrogen having access to eight electrons and each hydrogen having access to two ( this is why hydrogen only needs two). ) Given a name or chemical formula, tell whether it represents a binary ionic compound, an ionic compound with polyatomic ion(s), a binary covalent. How does the equation with acidified dichromate solution and with isopropyl alcohol (CH3CHOHCH3) differ from the oxidation of ethyl alcohol which is a primary alcohol, containing a –CH2OH group?.
vqkds3owe9yg, 9229xpa1ac, ih7888gvpp8mm, 0q4olknu3hfk61, zmzmvms9fz, njtvr0zm5m5, wbzx1cqc2bsej, mc5du97vbox, xe9arjij1cxi, n65w6ytwphhzwz3, ycwkdlxex27, t9ipiaxma2w, wq3r8okudti, gnnne0v8pswd4ry, g5a29dvlalwk84e, 6n4hrnnj3i6pc4, twg63ahs03isxr, gcmmeh45v5ra, zp827s52p564u, 1yjf4ele6plh, 6op2i8en4yvjxe, nqfdgvfo9wo0, 9kmatohelk4, axsa1k51h21omxj, lttkuvxc0mi, s93qx2n3n7ruhw